UPDATE – Still ongoing issue, works / does not work. Arg! %$#@
After some trial and error, here are the settings for SMTP for outlook.com using outlook 2010 without the Internet Connector installed. This is on and old Terminal Server that is still running Office 2010 but user unable to install new software, so manual configuration had to do.
NOTE: Strange however that I needed to use logon using outlook.com account info and not selecting use same as incoming on the Outgoing server tab.
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